WEBJul 1, 2006 · Direct coal liquefaction (DCL) converts solid coal (H/C ratio ≈ ) to liquid fuels (H/C ratio ≈ 2) by adding hydrogen at high temperature and pressures in the presence or absence of alyst.
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WEBOn the surface, it looks pretty much the same as the process of coal liquefaction. It is a thermochemical conversion process of organic material into liquid biocrude and coproducts. Depending on the process, it is usually conducted under moderate temperatures (300400°C, lower than coal liquefaction) and pressures (1020 MPa, similar or ...
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WEBDirect liquefaction (DCL) processes and technology for coal and biomass conversion. 2011, 105154. ... A new process for alytic liquefaction of coal using dispersed MoS2 alyst generated in situ with added H2O. Fuel 2000, 79 ... Mechanochemical effects in coal conversion. 1. Coal hydrogenation in gaseous hydrogen aided by mechanical .
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WEBHTL, also called hydrothermal upgrading, hydrothermal processing, and direct liquefaction (Xiu and Shahbazi 2012), is a thermochemical process that allows the conversion of biomass to liquids, generally carried out in the absence of oxygen and in the presence of a solvent, most of the times water. The fact that water is both solvent and ...
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WEBAug 11, 2021 · Hydrothermal liquefaction is one of the common thermochemical conversion methods adapted to convert highwater content biomass feedstocks to biofuels and many other valuable industrial chemicals. The hydrothermal process is broadly classified into carbonization, liquefaction, and gasifiion with hydrothermal .
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WEBAug 1, 1984 · The use of highcarbonbased feeds to produce alternative fuels and valueadded chemicals is discussed. Basic conversion chemistry, chemical structures of coal and lignin biomass are discussed, followed by process technologies for direct liquefaction, liquid quality, process control and modeling, advantages and limitations, .
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WEBJan 1, 1994 · Direct liquefaction (DCL) processes and technology for coal and biomass conversion. 2011, Advances in Clean Hydrocarbon Fuel Processing: Science and Technology ... Basic conversion chemistry, chemical structures of coal and lignin biomass are discussed, followed by process technologies for direct liquefaction, liquid .
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WEBJul 18, 2017 · For the most highly developed processes, coal conversion can be as high as 90% on a mineral ash free basis, with a C 5+ distillate yield up to 75% and hydrogen consumption of 5–7%wt. When an external alyst is used, it is typically some combination of cobalt, nickel, and molybdenum on a solid acid support such as silicaalumina [].DCL .
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WEBAdvances in Clean Hydrocarbon Fuel Processing || Direct liquefaction (DCL) processes and technology for coal and biomass conversion. Elsevier, pages 105154, 2011 ... (DCL) processes and technology for coal and biomass conversion Author. Burgess Clifford, C. Publisher. Elsevier Edition/series info. pages 105154, 2011 Year. 2011 .
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WEBAug 1, 2022 · The conversion routes of biomass are mainly summarized in Fig. biochemical conversion has been widely used for the production of biogas and ethanol fuel [18, 19], our article focuses on the thermochemical conversion routes in particular pyrolysis, hydrothermal liquefaction and gasifiion as these processes .
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WEBJan 12, 1998 · A previous paper has shown that direct coal liquefaction in the absence of a alyst consists of two distinct stages which are readily ... A kinetic model for the liquefaction processes based on these observations is introduced. ... Direct liquefaction (DCL) processes and technology for coal and biomass conversion. 2011, 105154. .
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WEBJan 23, 2015 · Coal liquefaction, currently termed coal to liquids (CTL) [], is a chemical process for producing synthetic transportation fuels from coal to replace or supplement conventional supplies of diesel oil and gasoline derived largely from petroleum [].Technologically, there are two primary routes for CTL production—direct coal .
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WEBMar 4, 2005 · As the cost of production is a key determinant of longterm viability, developing methods that reduce the cost of direct coal liquefaction has posed a challenge to scientists and industrial organizations worldwide. This paper summarizes recent developments in technology and processes and explores the overall economic .
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WEBDec 1, 2016 · Coal Conversion Processes. December 2016. DOI: / In book: KirkOthmer Encyclopedia of Chemical Technology. Authors: James G. Speight. To read the full ...
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WEBNov 1, 2022 · The cofeeding of coal and biomass and integrating high and lowtemperature processes can significantly improve the environmental performance of ICL [21], [22]. Coal to fuel ethanol (CTFE) is considered a promising substitute for gasoline in vehicles, but its environmental performances are much worse than those of fuel .
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WEBFeb 1, 2000 · Maximum conversion (98%) and maximum oil + gas yield (70%) from this coal were obtained by impregnating AHM onto coal and carrying out liquefaction in H2/tetralin system at 450 °C for 30 min.
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WEBReason for Discussion of Direct Liquefaction of Coals in Gasifipedia As the follow chat of Direkter Coal Liquefaction (DCL) explains, the fundamental procedure approach of DCL does not involve gasifiion at all. Therefore it would seem to live entirely leave of scope regarding Gasifipedia. However, the following considerations require this discussion of .
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WEBJan 12, 1998 · A previous paper has shown that direct coal liquefaction in the absence of a alyst consists of two distinct stages which are readily distinguishable with an appropriate short contact time liquefaction reactor and thermogravimetric analysis. The first stage, an extraction of liquefaction solventsoluble material in the coal, is very .
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WEBNov 8, 2023 · Liquefaction is one of the several technologies available for biomass conversion, alongside processes like pyrolysis, gasifiion, and fermentation. The liquefaction process involves heating the biomass feedstock in the presence of a solvent or a alyst to break down the complex organic molecules into simpler, liquid .
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WEBJan 15, 2023 · There are many liquefaction processes related to DCLS [26], [29], [31], [108], [109]. Several typical or highly referential liquefaction processes that have been reported are selected in this paper for introduction. As an illustration, a flow diagram of coal liquefaction process using syngas was proposed by Fu et al. [29], as shown in Fig. 14.
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WEBCharacterization of Oxygenated Species in Coal Liquefaction Products: An Overview. ... Z. R. Ismagilov. The relationship between the molecular composition of coal and the conversion of its organic matter during thermal dissolution. Carbon Letters 2022, 32 (4 ... (DCL) processes and technology for coal and biomass conversion. 2011 ...
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WEBMay 21, 1996 · Coal liquefaction conversion to tetralinsoluble products was determined by changes in ash content in the partially reacted coal relative to that of the unreacted coal. ... A Novel Process of Biomass Gasifiion for HydrogenRich Gas with Solid Heat Carrier: Preliminary Experimental Results. ... (DCL) processes and technology for .
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WEBAug 1, 2015 · Thermochemical conversion processes mainly include combustion, pyrolysis, gasifiion, and liquefaction [8], [9], [10], [11].Liquefaction is a lowtemperature (250–400 °C) and highpressure (5–20 MPa) thermochemical process during which the biomass is converted into three products, a biooil fraction (target product), a gas .
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WEBApr 27, 2020 · A comprehensive model of thermal conversion as a function of temperature, pressure and heating rate of biomass has been provided. For the most important, basic process, which is pyrolysis, five mechanisms of thermal decomposition kinetics of its components (lignin, cellulose, hemicellulose) were presented.
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WEBJul 1, 1990 · Mechanism of hydrogen transfer and role of solvent during heatingup stage of direct coal liquefaction. Fuel Processing ... Kinetics and activation energy of solvent swelling of coal altered by an ultrasoniionenhanced process. Korean Journal ... Direct liquefaction (DCL) processes and technology for coal and biomass conversion. .
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WEBJan 15, 2021 · Hydrothermal liquefaction is one of the most promising technologies to convert high moisture biomass into biofuels. However, understanding the liquefaction mechanism of different biomass fractions is still a challenge. The liquefaction of both lignin and cellulose is frequently studied, but the high diversity of biomass and processes .
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WEBJul 27, 2022 · Fundamentals of HTL. Hydrothermal Liquefaction (HTL), also known as hydrous pyrolysis (Jazrawi 2014; Goswami et al. 2020b), is thermochemical conversion of biomass in a hightemperature pressurized environment (Yang and Yang 2019), in the presence of hot compressed water at subcritical conditions, mainly into a liquid product .
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WEBDec 1, 2014 · The environmental footprint of coal liquefaction processes can usually be reduced by coprocessing coal and biomass and applying CO 2 capture and storage (CCS) technology but at the cost of higher ...
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WEBJan 1, 2023 · Direct coal liquefaction (DCL) commonly refers to alytic hydrogenation of coal in a recycled oil solvent at high pressures with a alyst. While a range of process configurations have been proposed, the most common version involves at least two high pressure slurry reactors in a series using a dispersed ironbased alyst and hydrogen ...
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WEBFeb 15, 2024 · In our previous study [14], [22], a staged conversion technology was proposed for the characteristics of lowrank coal. The asphaltene separated from the first stage reaction was hard to hydrocrack and need to be converted under strong alytic conditions, which was the key to improve the liquefaction efficiency of the whole process.
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WEBThis paper presents a brief state of the art review of direct coal liquefaction. The review includes important pilot scale processes available for the liquefaction an a brief description of the structure of coal and the chemistry, mechanism and available lumped kinetic models for the liquefaction process. It also includes some discussions on ...
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WEBApr 1, 2018 · As part of an ongoing project at Karlsruhe Institute of Technology (KIT), Germany, this work examines the liquefaction of varying feedstocks under conditions of the Bergius process of direct coal liquefaction by high pressure heterogeneous alytic this process onto renewable resources like lignin and lignin .
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WEBNov 1, 2019 · Therefore, the development of processes that would be able to convert biomass under milder reaction conditions (below 20 bar [101]) would be a step forward for the commercialization of lignocellulosic biomass conversion through liquefaction. However, the desired temperature range required for the process, 200–400 °C, .
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WEBMar 1, 2015 · The increasing demand for petroleum and the limited fossil fuel storage has urged great efforts and researches on improving current fuel and energy conversion technologies [1]. The coal liquefaction technology has become an effective way of clean utilization of coal for not only the preparation of high calorific value fuels [2], but also a ...
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WEBApr 1, 2020 · Hydrothermal liquefaction is the process of converting biomass into liquid oils in pressurized water environment (5–20 MPa) at 300–400 °C for longer residence time (–1 h) with biomasstowater ratio from 3:1 to 10:1 (Beckman and Elliott 1985). For woody and lignocellulosic biomass, feedstock pretreatment (particle size, contaminant ...
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